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Mn-dopant-induced effects in Zn1-xMnxO compounds

Riyadi S.a, Muafifa, Nugroho A.A.a, Rusydi A.a,b, Tjia M.O.a

a Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
b Institut für Angewandte Physik, Universitat Hamburg, Germany

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]An experimental study on Mn-dopant-induced effects in Zn 1-xMnxO was performed for samples with x = 0.02, 0.04, 0.06, and 0.08, which were prepared by solid state reaction at 1200 °C. The result of x-ray diffraction refinement analysis did not turn up evidence of MnxOy cluster inclusion over the entire doping range, while the structural parameter variations indicate a solubility limit of about 6% for Mn2+ and incorporation of Mn ions of higher valency at higher dopant levels. The magnetization data exhibit mostly intrinsic antiferromagnetic instead of ferromagnetic properties, as predicted by more recent theoretical works. The substitutional incorporation of the Mn in ZnO was further confirmed by the associated broad-band photoluminescence spectra. The suggested incorporation of Mn ions of higher valency at higher dopant concentration was also supported by the related x-ray photoemission data, and in agreement with a previous theoretical prediction. © IOP Publishing Ltd.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Cluster inclusions,Doping ranges,Ferromagnetic properties,Photoluminescence spectra[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1088/0953-8984/19/47/476214[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]