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Cyclic voltammetric study of chlorambucil in the presence of 4-chloro butyronitrile in aqueous solution
Setiyanto H.a, Saraswaty V.b, Hertadi R.a, Noviandri I.a, Buchari B.a
a Analytical Chemistry Research Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
b Research Centre for Chemistry, Indonesian Institute of Sciences, Indonesia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]Interactions of chlorambucil with water in the presence of 4-chloro butyronitrile has never been reported to be conducted electrochemically. We presented the investigation of electrochemical oxidation and reduction of chlorambucil in the presence of 4-chloro butyronitrile in aqueous solution using cyclic voltammetric technique. The results showed that the values of the anodic’s and cathodic’s peak currents of chlorambucil in the presence of 4-chloro butyronitrile in aqueous solution were higher than that without 4-chloro butyronitrile. The anodic’s and cathodic’s peak potentials of chlorambucil shifted to more negative value in the addition of this substance. The anodic’s peak shifted from 0.896 V to 0.855 V while the cathodic’s peak shifted from 0.788 V to 0.742 V. We found that the values of chemical reactivity of chlorambucil in aqueous solution, in the presence and the absence of 4-chloro butyronitrile were 0.4897 s -1 and 0.4485 s -1, respectively. These results strongly suggested that chlorambucil is easier to be oxidized in the presence of 4-chloro butyronitrile.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Aqueous solution,Chemical reactivity,Chlorambucil,Cyclic voltammetry,Nucleophile[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]