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Study of the adsorption kinetics and thermodynamic for the removal of Congo Red from aqueous solution using powdered eggshell

Zulfikar M.A.a, Setiyanto H.a

a Analytical Chemistry Research Group, Institut Teknologi Bandung, Indonesia

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]The effect of temperature on Congo Red (CR) removal using powdered eggshell has been studied. From experiment it can be seen that the CR removal using powdered eggshell increased with increasing temperature. The adsorption kinetic data of CR on powdered eggshell was well described by a pseudo-second-order model, with the kinetic constants in the range of 0.093 – 0.108 g mg-1 min-1. From both the intra-particle diffusion and Boyd kinetic models indicated that the CR adsorption process may be controlled by the intra-particle diffusion. Thermodynamic parameters data indicated that the CR sorption process was non-spontaneous and endothermic under the experimental conditions, with the Gibbs free energy (ΔG°) in the range of 2.33-0.93 kJ mol1, enthalpy (ΔH°) and entropy (ΔS0) of 7.21 kJ mol-1 and 17.55 J mol1, respectively and the activation energy was 14.98 kJ mol-1.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Adsorption,Congo red,Eggshell,Kinetic,Thermodynamic[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]