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A red emitting of manganese-doped boron carbon oxynitride (BCNO) phosphor materials: facile approach and photoluminescence properties
Nuryadin B.a, Permatasari F.A.b, Nuryantini A.Y.a, Faryuni I.D.c, Abdullah M.b, Iskandar F.b
a Department of Physics, UIN Sunan Gunung Djati Bandung, Bandung, 40614, Indonesia
b Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia
c Department of Physics, Faculty of Mathematics and Natural Sciences, Tanjungpura University, Pontianak, Indonesia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© The Royal Society of Chemistry.BCNO (boron carbon oxynitride) phosphors have attracted attention due to their non toxicity, simple synthesis process, and high quantum efficiency. However, the tunable emission, particularly a red emission, is still challenging to achieve. In the present study, a bright red emission (emission wavelength 620 nm under 365 nm UV excitation) of a manganese-doped BCNO (BCNO:Mn) phosphor synthesized by a solid state method is reported. Without Mn-doping, the BCNO phosphor exhibited a bright blue emission that can be ascribed to the closed-shell BO- and BO2- anions that act as luminescence center. Via Mn-doping, a red emission was exhibited that can be ascribed to the 4T1(4G) → 6A1(6S) transition from a new luminescence center of Mn2+ incorporated into the BCNO host lattice. The optimum red PL properties (λem: 611 nm, λex: 365 nm) were obtained with BCNO:Mn at a molar ratio of Mn/B at 0.71% mol/mol synthesized at 550 °C. We believe that the BCNO:Mn is a promising red-emitting phosphor for white light diodes.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Emission wavelength,High quantum efficiency,Luminescence centers,Phosphor materials,Photoluminescence properties,Red emitting phosphor,Solid state method,Tunable emissions[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This study was partly supported by a research grant Penelitian Unggul Integrasi Keilmuan (DIKTIS PUIK/37/2016) from the Ministry of Religious Affairs, Republic of Indonesia and Riset Desentralisasi PUPT (PN-7-11-2016) from the Indonesian Directorate General of Higher Education (DIKTI).[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1039/C6RA27018B[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]