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Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications
Iqbal M.a, Kaneti Y.V.a, Kim J.b,c, Yuliarto B.d, Kang Y.-M.e, Bando Y.a,f,g, Sugahara Y.h, Yamauchi Y.b,c,i
a International Research Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, 305-0044, Japan
b Key Laboratory of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China
c School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, 4072, Australia
d Department of Engineering Physics and Research Center for Nanoscience and Nanotechnology, Institute of Technology Bandung, Bandung, 40132, Indonesia
e Department of Energy and Materials Engineering, Dongguk University, Seoul, 04620, South Korea
f Institute of Molecular Plus, Tianjin University, Tianjin, 300072, China
g Australian Institute of Innovative Materials, University of Wollongong, North Wollongong, 2500, Australia
h Faculty of Science and Engineering, Waseda University, Tokyo, 169-8555, Japan
i Department of Plant & Environmental New Resources, Kyung Hee University, Yongin-si, 446-701, South Korea
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimPalladium (Pd) plays an important role in numerous catalytic reactions, such as methanol and ethanol oxidation, oxygen reduction, hydrogenation, coupling reactions, and carbon monoxide oxidation. Creating Pd-based nanoarchitectures with increased active surface sites, higher density of low-coordinated atoms, and maximized surface coverage for the reactants is important. To address the limitations of pure Pd, various Pd-based nanoarchitectures, including alloys, intermetallics, and supported Pd nanomaterials, have been fabricated by combining Pd with other elements with similar or higher catalytic activity for many catalytic reactions. Herein, recent advances in the preparation of Pd-based nanoarchitectures through solution-phase chemical reduction and electrochemical deposition methods are summarized. Finally, the trend and future outlook in the development of Pd nanocatalysts toward practical catalytic applications are discussed.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Active surface sites,Carbon monoxide oxidation,Catalytic applications,Catalytic reactions,Chemical reduction,Electrochemical deposition methods,Nanoarchitectures,Surface coverages[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]alloys,catalysis,electrochemical deposition,intermetallic structures,palladium nanoarchitectures[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This work was supported by Australian Research Council Future Fellowship (FT150100479). This work was partly supported by the International Energy Joint R&D Program of the Korea Institute of Energy Technology Evaluation and Planning, granted financial resource from the Ministry of Trade, Industry and Energy, Republic of Korea (No. 20168510011350). M.I. thanks the Indonesia Endowment Fund for Education (LPDP) for the financial support. Y.V.K. thanks the Japan Society for Promotion of Science for providing the standard postdoctoral fellowship.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1002/smll.201804378[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]