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Fabrication of Flexible Graphite Film Using a Mechanical Method and Its Application in Tio2/Graphite Solar Cell as a Flexible Counter Electrode
Rahman D.Y.a, Utami F.D.a, Margaretta D.O.a, Sustini E.a, Abdullah M.a
a Department of Physics, Faculty of Mathematical and Natural Sciences, Bandung Institute of Technology, Bandung, 40132, Indonesia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2019 IOP Publishing Ltd. All rights reserved.We have successfully fabricated solar cell using flexible counter electrode of graphite powder. TiO2 / graphite suspension was simply poured onto heated Fluorine Tin Oxide (FTO) substrate and kept heated at 200°C for 2 hours. PVA.LiOH polymer electrolyte was employed as a positive charge transfer medium. The counter electrode was made of graphite powder which is manually deposited on transparent plastic using tube-shaped metal which its surface covered with tissue of 2 mm thick. Graphite powder was deposited by straight motion of 20 movements for one coating or one layer. The same activity was repeated on the stacked film to increase the conductivity of the film. Resistivity and transmittance measurement of the film was performed by four-point probe method and UV-Vis equipment respectively. The film thickness and 2-D porosity were measured using an electronic microscope and ImageJ software orderly. The film resistivity and transmittance gradually decreased with the increase of coating number and reached the resistivity of 0.35 Ω.cm and transmittance of 5% for 40 times of coating. At the same time, the film thickness was saturated at the 30 times coating and reached the thickness of 9.4 μm. The film 2-D porosity which indicated how well the surface of the film covered the graphite also decreased to reach the film porosity of 18%. The most conductive film (40 times coating) was used as a flexible counter electrode in TiO2/graphite solar cell. The efficiency of this structure was 0.4 %, a reasonable efficiency achievement for a cheap material and easy method used.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Counter electrodes,Electronic microscopes,Fluorine tin oxides,Four-point probe method,Mechanical methods,Polymer electrolyte,Transmittance measurements,Transparent plastics[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This work was supported by fellowship grant from Indonesia Endowment Fund for Education (LPDP). The PMDSU fellowships from the Ministry of Research, Technology and Higher Education, Republic of Indonesia F.D.U. is highly acknowledged. This work was also supported by KK Research Grant from Bandung Institute of Technology 2019.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1088/1757-899X/599/1/012004[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]