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Preparation of Ni- and Mo-based catalysts supported on γ-Al2O3 for hydrocracking of Calophyllum inophyllum oil
Trisunaryanti W.a, Kartika I.A.b, Mukti R.R.c, Hartati H.d, Triyono T.a, Widyawati R.a, Suarsih E.a
a Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia
b Department of Agro-Industrial Technology, Institut Pertanian Bogor, Bogor, Indonesia
c Department of Chemistry, Institut Teknologi Bandung, Bandung, Indonesia
d Department of Chemistry, Universitas Airlangga, Surabaya, Indonesia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group.A simple method for dispersing supported metal catalysts comprising Ni and/or Mo supported on γ-Al2O3 was performed by wet impregnation. This study investigated the preparation, characterization, and catalytic application of monometallic catalyst of NiO and MoO and bimetallic catalyst NiO–MoO supported on γ-Al2O3 for hydrocracking of Calophyllum inophyllum oil (CIO). Two variations of metal content were set at 7.5 wt% (marked as x) and 15.0 wt% (marked as y); thus, the prepared catalysts were denoted as yNiO/γ-Al2O3, yMoO/γ-Al2O3, xNiOxMoO/γ-Al2O3, and yNiOyMoO/γ-Al2O3. Among the catalysts investigated, yNiOyMoO/γ-Al2O3 exhibited the best performance in hydrocracking of CIO with total metal content, acidity, and specific surface area of 13.73 wt%, 9.13 mmol g−1, and 104.31 m2 g−1, respectively, and produced 69.44 wt% liquid product (biofuel). The gas chromatography–mass spectroscopy analysis result of the liquid product showed that the biofuel was composed of 38.54 wt% gasoline fraction (C5–C12), 9.80 wt% kerosene fraction (C13–C15), 17.69 wt% diesel fuel fraction (C16–C19), and 3.43 wt% heavy oil (>C19).[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Bimetallic catalysts,Calophyllum inophyllum,Catalytic applications,Gasoline fractions,Mass spectroscopy,Monometallic catalysts,Supported-metal catalysts,Wet impregnation[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Calophyllum inophyllum,hydrocracking,molybdenum,Nickel,γ-Al2O3[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1080/17597269.2019.1669871[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]