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Kinetic studies of turpentine isomerization using hydrochloric acid and acetic acid as catalysts
Azis M.M.a, Qani’A F.R.a, Pratiwi S.I.a, Kristanto J.a, Purwono S.a, Indarto A.b
a Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, 55281, Indonesia
b Department of Chemical Engineering, Institut Teknologi Bandung, Bandung, 40132, Indonesia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© Published under licence by IOP Publishing Ltd.Turpentine is a non-wood forest product derived from pine trees. Turpentine oil can be produced from the distillation of pine tree sap (family Pinaceae). The main component of turpentine is α-pinene, and turpentine isomerization may produce various derivative products. The objective of the present study was to investigate the isomerization products of turpentine oil with two acid catalysts: hydrochloric and acetic acid. Here, the influence of acid concentration was investigated by using various concentrations of hydrochloric and acetic acid concentrations between 0.4 to 1 M. Further, the combination of acetic acid and hydrochloric acid as catalyst was also investigated by varying the molar ratio of HCl:Acetic Acid=1 : 0.5 and 1:1. The experiments were carried out in a batch reactor equipped with heater, condenser, and stirrer. The reaction temperatures were maintained at 150°C and reaction time of 6 h. The resulting products from turpentine isomerization were analyzed using GC-MS. The results showed that the largest isomerization product obtained with HCl and combination of HCl:H.Acetic was trans sabinene hydrate. Additional products that could be detected varied among α-terpinolene, α-terpineol, α-terpinene, γ-terpinene and δ-carene. The experimental data showed that α-pinene conversion as high as 62, 63 and 57% were obtained by using HCl concentrations of 0.4, 0.7 and 1 M, respectively. In addition, the use of HCl:H.Acetic=1 :0.5 and 1:1 gave final conversion of 63 and 61%. The modeling results showed the kinetic model for pinene conversion for both catalysts was IMG ALIGN=MIDDLE ALT=$\frac{dX}{dt}=0.5222\cdot {(1-X)}^{2.5210}{C}-{\mathrm{HCl}}-0.2233\cdot {(1-X)}^{4.5300}{C}-{\mathrm{HAc}}$ SRC=MSE-823-1-012042-ieqn1.gif/[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]We would like to thank the financial support from the Department of Chemical Engineering, UGM which enabled us to conduct this study in Bandung. Secondly, we would also like to thank both the Department of Chemical Engineering UGM and ITB that allows the realization of the present study. We would also like to thank lham Ardiyanto Putra, Yestria Yaswari, and Fira for their invaluable help during the experimental works as well as result interpretations.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1088/1757-899X/823/1/012042[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]