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Spectroscopic study of Nd3+ ion-doped Zn-Al-Ba borate glasses for NIR emitting device applications
Djamal M.a,b, Yuliantini L.a, Hidayat R.a, Rauf N.c, Horprathum M.d, Rajaramakrishna R.e, Boonin K.e,f, Yasaka P.e,f, Kaewkhao J.e,f, Venkatramu V.g,h, Kothan S.i
a Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia
b Physics Study Program, Department of Science, Institut Teknologi Sumatera, Lampung, 35365, Indonesia
c Department of Physics, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245, Indonesia
d Optical Thin-Film Laboratory, National Electronics and Computer Technology Center, Pathumthani, 12120, Thailand
e Department of Post Graduate Studies & Research in Physics, The National College, Bengaluru, 560070, India
f Center of Excellence in Glass Technology and Materials Science (CEGM), Nakhon Pathom Rajabhat University, Nakhon Pathom, 73000, Thailand
g Department of Physics, Yogi Vemana University, Kadapa, 516 005, India
h Department of Physics, Krishna University Dr. MRAR PG Centre, Nuzvid, 521 201, India
i Center of Radiation Research and Medical Imaging, Department of Radiologic Technology, Faculty of Associated Medical Sciences, Chiang Mai University, Chiang Mai, 50200, Thailand
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2020 Elsevier B.V.Trivalent neodymium (Nd3+) -doped Zn-Al-Ba borate glasses of composition (60-x)B2O3+20BaO+10Al2O3+10ZnO + xNd2O3(x = 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol%) were prepared by a conventional melt-quenching technique and studied their physical, structural, optical and luminescence properties. The amorphous nature of the glasses has been confirmed by X-ray diffraction patterns. The EDAX data shows percent mass of elements of the glass system. FTIR spectra confirm the formation of BO3 and BO4 groups in the glass structure and compared them with Raman spectra. The Judd-Ofelt theory was adopted to analyze the radiative properties of Nd2O3 –doped glasses to derive oscillator strengths (f), JO parameters (Ωλ=2,4,6), stimulated emission cross-sections (σe), radiative transition probabilities (AR), and branching ratios (βR) of various transitions of Nd3+ ions. The lifetime of the 4F3/2 level of Nd3+ ions in the glasses decreases with the increase of Nd2O3 concentration due to the shortened distance between Nd3+ ion in the glass structure. The strongest emission intensity is found at 1056 nm (4F3/2 → 4I11/2 transition) when excited by 808 nm. The optimum concentration of Nd2O3 in the studied glasses is found to be 1.0 mol% based on luminescence intensity. All these results were compared with reported research of Nd3+:glasses to determine the lasing potentiality of studied glasses.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Luminescence intensity,Luminescence properties,Melt quenching techniques,Optimum concentration,Radiative properties,Radiative transition probabilities,Spectroscopic studies,Stimulated emission cross section[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Borate glass,IR emitting Material,Judd-ofelt theory,Luminescence,Neodymium[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][{‘$’: ‘This work has been supported by Riset ITB 2019 (No. 91I/I1.C01/PL/2019) and WCU-ITB 2019 (No. 350C/SK/I1.B02/2019). J. Kaewkhao, K. Boonin, P. Yasaka and Ms. Lia Yuliantini would like to express her sincerely thank National Research Council of Thailand (NRCT) and Nakhon Pathom Rajabhat University (NPRU) for supporting this research and National Electronics and Computer Technology Center (NECTEC), Thailand for Raman measurement. This research was partially supported by Chiang Mai University. One of the authors Venkatramu is grateful to Department of Science and Technology (DST), New Delhi for the sanction of research project (No. INT/PORTUGAL/P-04/2017) under India-Portugal bilateral scientific and technological cooperation.’}, {‘$’: ‘This work has been supported by Riset ITB 2019 (No. 91I/I1.C01/PL/2019 ) and WCU-ITB 2019 (No. 350C/SK/I1.B02/2019 ). J. Kaewkhao, K. Boonin, P. Yasaka and Ms. Lia Yuliantini would like to express her sincerely thank National Research Council of Thailand (NRCT) and Nakhon Pathom Rajabhat University (NPRU) for supporting this research and National Electronics and Computer Technology Center (NECTEC) , Thailand for Raman measurement. This research was partially supported by Chiang Mai University . One of the authors Venkatramu is grateful to Department of Science and Technology (DST), New Delhi for the sanction of research project (No. INT/PORTUGAL/P-04/2017 ) under India-Portugal bilateral scientific and technological cooperation.’}][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1016/j.optmat.2020.110018[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]