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Nanofiltration membrane cross-linked by m-phenylenediamine for dye removal from textile wastewater

Gunawan F.M.a, Mangindaan D.b, Khoiruddin K.c, Wenten I.G.c

a Chemical Engineering Department, Faculty of Industrial Technology, Parahyangan Catholic University, Bandung, 40141, Indonesia
b Food Technology Department, Faculty of Engineering, Bina Nusantara University, Jakarta, 11480, Indonesia
c Chemical Engineering Department, Institut Teknologi Bandung, Bandung, 40132, Indonesia

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2018 John Wiley & Sons, Ltd.In this work, m-phenylenediamine (MPD) is used to prepare cross-linked polyetherimide (PEI)-based nanofiltration (NF) membrane for treatment of dye containing wastewater. The effects of dope solution composition, cross-linking time, and dye concentration on membrane performance are investigated. Results indicate that the rejection of dye is increased with the increase of acetone concentration in the dope solution, cross-linking time, and dye concentration. Meanwhile, membrane flux showed the opposite trend. With the aid of SEM and FTIR analysis, the cross-linking between MPD and PEI is confirmed. The cross-linked membrane has thicker and dense selective layer compared to the unmodified membrane. The cross-linked NF membrane (PEI: 15 wt%; acetone: 20 wt%; cross-linking time: 10 minutes) showed good performance in filtration of synthetic dye wastewater (Reactive Red 120, 1500 ppm) with 98% dye rejection and 0.013 L m−2 hour−1 of flux at relatively low operating pressure (60 psi).[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Acetone concentrations,Cross linked membranes,Dye removal,Membrane performance,Membrane preparation,Operating pressure,Synthetic dye wastewaters,Textile wastewater[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]cross-linking,dye removal,membrane preparation,nanofiltration,textile wastewater[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]We acknowledged Ms. Kangjia Lu, Mr. Yingnan Feng, and Prof. Tai Shung Chung of Department of Chemical and Biomolecular Engineering, National University of Singapore, for the valuable assistance in preparing this manuscript.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1002/pat.4473[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]