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SOFC composite electrolyte based on LSGM-8282 and zirconia or doped zirconia from zircon concentrate

Rahmawati F.a,b, Prijamboedi B.a, Soepriyanto S.a, Ismunandara

a Inorganic and Physical Chemistry Research Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
b Research Group of Solid State and Catalysis, Chemistry Department, Sebelas Maret University, Indonesia

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]The aim of this research is to study zirconia-based electrolyte materials to increase the commercial value of zircon concentrate as a side product of tin mining industries. Synthesis of CaO-Y 2O 3-ZrO 2 (CYZ) and 8mol% Y 2O 3-ZrO 2 (8YSZ) was carried out by solid state reaction. The result shows that ZrO 2 presents in tetragonal phase. Doping of Y 2O 3 into ZrO 2 allows a phase transformation from tetragonal into cubic structure with small percentage of monoclinic phase. Meanwhile, doping of CaO-Y 2O 3 allows a phase transformation into a single cubic phase. These phase transformations enhance the ionic conductivity of the material. Introduction of 10wt% of LSGM-8282 into CYZ (CYZ-L90:10) allows further improvement of inter-grain contact shown by SEM morphological analysis and leads to the enhancement of ionic conductivity. © 2012 University of Science and Technology Beijing and Springer-Verlag Berlin Heidelberg.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Composite electrolytes,Cubic structure,Doped zirconia,Electrolyte material,Inter-grain,LSGM electrolyte,Monoclinic phase,Morphological analysis,Side products,Single cubic phase,Tetragonal phase[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Ionic conductivity,LSGM electrolyte,Phase transformations,Solid electrolytes,Solid oxide fuel cells (SOFC),Zirconia[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This work was supported by the Directorate General of Higher Education, Republic of Indonesia through Hibah Desertasi Doktor and Riset KK ITB. Authors greatly acknowledge for this support. We also acknowledge to Prof. Gyeong Man Choi and the members of the Fuel Cell Laboratory, Pohang University of Science and Technology (POSTECH) for all the assistance provided.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1007/s12613-012-0640-0[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]