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PEO/PVA/LiOH Solid Polymer Electrolyte Prepared via Ultrasound-assisted Solution Cast Method

Putri R.M.a, Sundari C.D.D.a,b, Floweri O.a, Mayangsari T.R.c, Ivansyah A.L.a, Santosa S.P.a, Arcana I.M.a, Iskandar F.a

a Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia
b Department of Chemistry Education, UIN Sunan Gunung Djati Bandung, Bandung, 40292, Indonesia
c Department of Chemistry, Universitas Pertamina, Jakarta, 12220, Indonesia

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2020Most solid polymer electrolytes (SPEs) still suffer from low ionic conductivity at room temperature, which may be caused by the inhomogeneity of polymer blend and Li-salt. Here, polyethylene oxide (PEO), polyvinyl alcohol (PVA), and lithium hydroxide (LiOH) SPEs were prepared by an ultrasonic method to improve the ionic conductivity and shorten the synthesis time. This procedure has successfully yielded a flexible, transparent, and homogeneous SPEs, which were thermally stable at fairly high temperature as revealed from thermogravimetric analysis (TGA). These samples also showed relatively high ionic conductivity at room temperature with the highest conductivity of 1.25 × 10−4 S/cm and low activation energy of 0.253 eV demonstrated by sample with 2 wt% LiOH loading. Moreover, this sample was also stable in the measured voltage range, i.e., -5 to 5 V. DFT calculation showed that strong intermolecular charge transfer was present in the interaction between Li+ ion with PVA and PEO chain.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Intermolecular charge transfer,Lithium hydroxide,Low-activation energy,Poly (vinyl alcohol) (PVA),Polyethylene oxide (PEO),Solid polymer electrolytes,Solution cast methods,Ultrasonic methods[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Lithium hydroxide (LiOH),Polyethylene oxide (PEO),Polyvinyl alcohol (PVA),Solid polymer electrolytes (SPEs),Ultrasonication[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][{‘$’: ‘This work was supported by the Institute for Research and Community Services (LPPM) Institut Teknologi Bandung through Riset KK, 2020 ITB Research Program (1R/I1.C01/PL/2020) and the Sustainable Higher Education Research Alliances (SHERA) program, USAID. C. D. D. Sundari would like to thank the Endowment Fund for Education (LPDP) of the Ministry of Finance, Indonesia, for the Doctoral Program funding. O. Floweri would like to thank ITB World Class University (WCU) Post-doctoral program.’}, {‘$’: ‘This work was supported by the Institute for Research and Community Services (LPPM) Institut Teknologi Bandung through Riset KK, 2020 ITB Research Program (1R/I1.C01/PL/2020) and the Sustainable Higher Education Research Alliances (SHERA) program, USAID. C. D. D. Sundari would like to thank the Endowment Fund for Education (LPDP) of the Ministry of Finance, Indonesia, for the Doctoral Program funding. O. Floweri would like to thank ITB World Class University (WCU) Post-doctoral program.’}][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1016/j.jnoncrysol.2020.120549[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]