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Proton conductivity of CsH2PO4•WPA composites at intermediate temperatures

Insani E.K.a,b, Nguyen V.H.a, Kawamura G.a, Hamagami J.-I.a, Sakai M.a, Matsuda A.a, Yuliarto B.b

a Department of Material Science, Toyohashi University of Technology, Japan
b Department of Engineering Physics, Institut Teknologi Bandung, Indonesia

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]CsH2PO4 and H3PW12O 40•6H2O (WPA•6H2O) were mechanically milled by using planetary ball mill to obtain xCsH2PO4 – (1-x)WPA•6H2O (%mol) composites. Characterizations of the composites indicate that there were changes of structure of CsH 2PO4•WPA composite after mechanical milling. 1H MAS NMR measurements suggested a hydrogen bond was newly developed between CsH2PO4 and WPA which correlated with conductivity of the composites. 95CsH2PO4•5WPA shows the highest conductivity at 70-170°C range of temperature. The mechanical milling succeed to increase the conductivity under non-humidified atmosphere and intermediate temperature. © 2010 American Institute of Physics.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]CsH2PO4,electrolyte,fuel cell,mechanical milling,proton conductivity[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1063/1.3515558[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]