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Crystal structure and magnetic properties of non-stoichiometric co2mnga heusler alloy

Akbar M.Y.P.a, Sihombing R.R.a, Sakai A.c, Nugroho A.A.a, Nakatsuji S.b

a Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, Indonesia
b The Institute for Solid State Physics, The University of Tokyo, Kashiwa, Japan
c

[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2019 Trans Tech Publications Ltd, Switzerland.Crystal structure and magnetic properties of Heusler-alloy Co2MnGa were examined systematically using non-stoichiometric compositions of Co and Mn element from the Czochralski as-grown single crystal samples. The crystalline structure of each sample was characterized by means of X-ray powder diffraction technique. Each sample was treated with and without heat treatment at 923 K for 10 hours. The effects of Co and Mn excess were observed in the lattice constants for both treatments. The L21-type crystal structure was observed only for the heat-treated samples. The changes in lattice constants are attributed to the substitution of atomic sites. The excess of Co tends to decrease the crystal volume, in opposite to the excess of Mn. In order to investigate the Slater-Pauling rule in the non-stoichiometric samples, the saturation magnetic moments were measured from the field-dependent magnetization measurement for the as-grown samples at 2 K. The deviation from the Slater-Pauling rule was found in the lower concentration of valence electron which associated to the lower total fraction of both Co and Mn. This indicates that the magnetic interactions of these materials cannot only be contributed to the number of valence electron.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Co2MnGa,Crystalline structure,Field-dependent magnetization,Non-stoichiometric,Non-stoichiometric composition,Saturation magnetic moments,Single crystal samples,Slater-Pauling rule[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Co2MnGa,Lattice constant,Non-stoichiometric,Saturation magnetization,Slater-Pauling rule[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.4028/www.scientific.net/MSF.966.319[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]