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Highly active Ni-promoted mesostructured silica nanoparticles for CO2 methanation
Aziz M.A.A.a, Jalil A.A.a, Triwahyono S.a, Mukti R.R.b, Taufiq-Yap Y.H.c, Sazegar M.R.a
a Institute of Hydrogen Economy, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, Malaysia
b Division of Inorganic and Physical Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Indonesia
c Catalysis Science and Technology Research Centre, Faculty of Science, Universiti Putra Malaysia, Malaysia
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]Mesostructured silica nanoparticles (MSN) and Ni loaded onto MSN (Ni/MSN) for the methanation of CO2 were prepared by the sol-gel and impregnation methods. Catalytic testing was conducted in the temperature range of 423-723K under atmospheric pressure in the presence of H2. Ni supported on MSN was compared with others types of support such as MCM-41 (Mobile Crystalline Material), HY (protonated Y zeolite), SiO2 and γ-Al2O3. The activity of CO2 methanation followed the order: Ni/MSN>Ni/MCM-41>Ni/HY>Ni/SiO2>Ni/γ-Al2O3. The nitrogen physisorption and pyrrole adsorbed IR spectroscopy results indicated that the high activity of Ni/MSN is due to the presence of both intra- and inter-particle porosity which led to the high concentration of basic sites. In addition, the correlation between N-H band intensity and the turnover frequency revealed that the methanation activity increased with increasing of the concentration of basic sites. The presence of defect sites or oxygen vacancies in MSN was responsible for the formation of surface carbon species, while Ni sites dissociated hydrogen to form atomic hydrogen. The surface carbon species then interacted with atomic hydrogen to form methane. The Ni/MSN catalyst performed with good stability and no deactivation up to 200h. © 2013 Elsevier B.V.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Atomic hydrogen,Catalytic testing,Impregnation methods,Mesostructured silica,Nitrogen physisorption,Particle pores,Temperature range,Turnover frequency[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text]Basicity,CO2 methanation,Intra-inter particle pores,Ni/MSN,Oxygen vacancy[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This work was supported by Ministry of Science, Technology and Innovation , Malaysia through EScienceFund Research Grant no. 03-01-06-SF0987 , MyPhd Scholarship (Muhammad Arif Ab Aziz) from Ministry of Higher Education , Malaysia and the Hitachi Scholarship Foundation for the Gas Chromatograph Instruments Grant.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1016/j.apcatb.2013.09.015[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]