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The effect of crystallinity on the surface modification and optical properties of ZnO thin films
Purbayanto M.A.K.a, Rusydi A.b, Darma Y.a
a Department of Physics, Institut Teknologi Bandung, Bandung, 40132, Indonesia
b Singapore Synchrotron Light Source, National University of Singapore 5 Research Link, Singapore, 117603, Singapore
[vc_row][vc_column][vc_row_inner][vc_column_inner][vc_separator css=”.vc_custom_1624529070653{padding-top: 30px !important;padding-bottom: 30px !important;}”][/vc_column_inner][/vc_row_inner][vc_row_inner layout=”boxed”][vc_column_inner width=”3/4″ css=”.vc_custom_1624695412187{border-right-width: 1px !important;border-right-color: #dddddd !important;border-right-style: solid !important;border-radius: 1px !important;}”][vc_empty_space][megatron_heading title=”Abstract” size=”size-sm” text_align=”text-left”][vc_column_text]© 2020 the Owner Societies.We have studied the effects of crystallinity on the emergence of porous morphology and strong green emission in ZnO thin films after H2 annealing treatment. The unique multiple-stacked porous structure is observed after performing H2 annealing treatment on the film with low crystallinity. However, the annealed high-crystallinity film exhibits surface morphology with a shallow porous structure, as revealed by SEM images. To study the effects of these unique porous structures on the optical properties, photoluminescence (PL) spectroscopy, Raman spectroscopy, spectroscopic ellipsometry, and X-ray photoelectron spectroscopy (XPS) are conducted. The multiple-stacked porous structure produces strong green emission as compared to the shallow porous structure centered at 2.5 eV, as detected by PL. Here, the green emission originates from the electronic transition related to the oxygen vacancy (VO). XPS spectra show that the high density of VO located on the multiple-stacked porous surface is much higher as compared to that for the shallow porous structure due to a high surface-to-volume ratio. The results show that the multiple-stacked porous structure has the potential to enhance the functionality of ZnO for applications in light-emitting.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Author keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Indexed keywords” size=”size-sm” text_align=”text-left”][vc_column_text][/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”Funding details” size=”size-sm” text_align=”text-left”][vc_column_text]This work was supported by Ministry of Research Technology and Higher Education of Republic of Indonesia (Kemenristekdikti) 2019 and ITB research program 2019. Authors also thank to J Ding and O Chichvarina from Department of Materials Science and Engineering NUS for their help.[/vc_column_text][vc_empty_space][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][vc_empty_space][megatron_heading title=”DOI” size=”size-sm” text_align=”text-left”][vc_column_text]https://doi.org/10.1039/c9cp05464b[/vc_column_text][/vc_column_inner][vc_column_inner width=”1/4″][vc_column_text]Widget Plumx[/vc_column_text][/vc_column_inner][/vc_row_inner][/vc_column][/vc_row][vc_row][vc_column][vc_separator css=”.vc_custom_1624528584150{padding-top: 25px !important;padding-bottom: 25px !important;}”][/vc_column][/vc_row]